Which looks correct.
However – according to httpFox – the server is actually looking for a Type of ‘text/problem-with-post-edit-buttontml’ NOT a Type of ‘text/css’. And it seems to me that having not found a file of type html the server is responding with a 500 error.
Now I am no expert in this arena but I have checked with several sites and Simple:Press and in al cases text/css is what the server is asked for and what it responds with except – for yours. And this is on your dev server.
Someone out there knows the reason and the answer for this but I am afraid it isn’t me! Although I will do some Googling after my dinner….