You will need to add it to your custom theme. There is an explanation of the code and an example here in our Codex:
https://simple-press.com/documentation/codex/plugins/our-plugins/available-plugins/subscriptions/#sp_SubscriptionsSubscribeForumButton
This will need to go in the spForumView.php template. Normally it would appear beside the add topic button so go down and find the block of code named the pageLinks section. By default and with the addition of the forum subscribe button, the code should now like:
# Start the 'pagelinks' section
# ----------------------------------------------------------------------
sp_SectionStart('tagClass=spPlainSection', 'pageLinks');
sp_TopicNewButton('tagId=spTopicNewButtonBottom&tagClass=spButton spRight', __sp('Add Topic'), __sp('Start a new topic'), __sp('This forum is locked'), __sp('No permission to start topics'));
sp_SubscriptionsSubscribeForumButton('tagClass=spSubscriptionsSubscribeForumButton spButton spRight', 'Subscribe', 'UnSubscribe','Subscribe to this forum', 'UnSubscribe from this forum');
sp_TopicIndexPageLinks('', __sp('Page: '), __sp('Jump to page %PAGE% of topics'), __sp('Jump to page'));
sp_InsertBreak();
sp_SectionEnd('', 'pageLinks');